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Optimization of Process of Hydrogenation Naphthalene by Hierarchical Porous Ni
2P/TiO
2⁃Al
2O
3
Liu Jin,Yang Lina,Wu Jing,Li Jian
The carrier of hierarchical porous TiO
2⁃Al
2O
3 and the catalyst Ni
2P/TiO
2⁃Al
2O
3 were prepared. The catalytic performance of the Ni
2P/TiO
2⁃Al
2O
3 was compared with the N
i2P loaded on the mesoporous Al
2O
3 and γ⁃Al
2O
3. The influence of the technological conditions, including reaction temperature, hydrogen oil ratio, mass space velocity and reaction pressure, were investigated by Orthogonal test and single factor exploration, respectively. The optimized technological conditions were obtained. The results showed that the hydrogenation catalyst Ni
2P/TiO
2⁃Al
2O
3 possessed more excellent de⁃aromatic rate and the selectivity of decahydronaphthalene compared with the ordinary catalyst of Ni
2P/γ⁃Al
2O
3 and Ni
2P/Al
2O
3. For the de⁃aromatic rate and the selectivity of decahydronaphthalene, the reaction pressure and temperature had more significantly affection to the hydrogen / oil ratio and the mass space velocity. According to the results of orthogonal test, the optimum reaction conditions of the hierarchical porous Ni
2P/TiO
2⁃Al
2O
3 catalyst in the hydrodeaphthalene reaction were investigated. The reaction temperature was 300 ℃, the reaction pressure was 4 MPa, the hydrogen / oil ratio was 500, and the mass space velocity was 1 h-1. The removal rate of naphthalene and the selectivity of decahydronaphthalene reached the highest, which were 99.2% and 72.0%, respectively.
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